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Catalog/Ghrelin

Ghrelin

Also known as Lenomorelin · the hunger hormone · acyl-ghrelin

The only hormone that makes you hungry — a stomach peptide, uniquely fatty-acid-modified, that drives appetite and also releases growth hormone.

Research refreshed

Overview

Ghrelin is a 28-amino-acid hormone made mainly in the stomach and best known as the body’s principal hunger signal — levels rise before meals and fall after eating. It is biochemically unusual: it requires an octanoyl (C8 fatty-acid) group attached to its third residue to be active, the only known hormone modified this way. Beyond appetite, ghrelin is a potent releaser of growth hormone, which links it to the secretagogue peptides elsewhere in this catalog.

Background

Almost every appetite hormone tells you to stop eating; ghrelin is the one that tells you to start. Secreted by the stomach when it is empty, it rises in the run-up to a meal, drives the sensation of hunger through hypothalamic feeding circuits, and falls once you have eaten. That makes it the orexigenic counterweight to satiety hormones like leptin, amylin, and the incretins — and a natural target for the opposite therapeutic goal: stimulating appetite in wasting conditions.

Its defining oddity is chemical. Ghrelin is the only human hormone known to carry an O-acyl fatty-acid modification — an octanoyl group esterified to the serine at position 3 by a dedicated enzyme (ghrelin O-acyltransferase, GOAT). Without that fatty acid the peptide cannot activate its receptor. This makes the GOAT enzyme an unusual drug target and the acylation a defining feature of how the hormone is studied and measured (acyl- versus des-acyl ghrelin).

Ghrelin’s second action is on growth hormone: it is the endogenous ligand of the growth-hormone secretagogue receptor, the same receptor hit by synthetic GHRPs such as ipamorelin and hexarelin found elsewhere in this catalog — so ghrelin is, in effect, the natural template those drugs imitate. Therapeutically the interest runs toward appetite stimulation: ghrelin-receptor agonists (anamorelin, relamorelin) have been studied for cancer cachexia and gastroparesis, making the hunger hormone a candidate where too little appetite is the problem.

Mechanism

Agonist at the growth-hormone secretagogue receptor (GHSR-1a). The octanoyl modification (added by the enzyme GOAT) is required for receptor binding. Activation stimulates appetite via hypothalamic NPY/AgRP neurons and triggers growth-hormone release from the pituitary.

Key research findings

  • Appetite — the principal circulating hunger signal; rises before meals and stimulates feeding via hypothalamic NPY/AgRP neurons.
  • Growth hormone — the endogenous ligand of GHSR-1a, the receptor targeted by synthetic secretagogues (ipamorelin, hexarelin).
  • Cachexia — ghrelin-receptor agonists (anamorelin) studied to stimulate appetite and lean mass in cancer-related wasting.
  • Unique acylation — the only human hormone requiring an octanoyl fatty-acid modification (via GOAT) for activity; the enzyme is a distinctive drug target.
  • Energy balance — acts opposite to satiety hormones such as leptin and amylin in body-weight regulation.

How Ghrelin is made

Behind every vial of Ghrelin is the same exacting pipeline every research peptide runs — but the chemistry plays out differently for this molecule. Here is how Ghrelin, specifically, is brought into being.

  1. On paper first

    On paper, Ghrelin weighs in at roughly 3,370.9 daltons. Before a single bond is made, the target sequence, salt form, and purity threshold are written down as the contract the finished material must meet.

  2. Built residue by residue

    Ghrelin is built one protected residue at a time by solid-phase synthesis, each cycle a deprotection, a coupling, and a wash. It also carries fatty-acid acylation, an extra step beyond a plain chain that adds both capability and cost.

  3. Purity is won here

    The crude mixture — Ghrelin plus its deletions and side products — is then separated on preparative HPLC, and where the cut is taken decides the difference between a genuinely pure peptide and a barely-passable one.

  4. Proven, then protected

    A real batch of Ghrelin proves itself: identity confirmed by mass spectrometry against its ~3,370.9 Da, purity read directly off an analytical HPLC trace, water and counterion content measured. That batch-specific certificate of analysis is the only honest way to know what is actually in a vial of Ghrelin — and a short, cold, accountable chain of custody is how that purity survives the trip to your bench.

Walk the full synthesis pipeline

Handling, storage & why purity is hard

The standout synthetic challenge in this class: activity requires an O-octanoyl ester on the Ser3 hydroxyl — the only such acylation among human hormones (installed biologically by ghrelin O-acyltransferase, GOAT). Standard solid-phase synthesis assembles the 28-mer, but installing and preserving the acid- and base-labile octanoyl ester demands orthogonal side-chain protection and a deliberately mild final deprotection/cleavage, since the unmodified by-product (des-acyl ghrelin) is inactive. The acylation is the purity-defining step, and acyl-vs-des-acyl ratio is the assay that matters most.

Demanding synthesisFatty-acid acylation

Don't judge a vial by its cake. A fluffy, good-looking lyophilized powder reflects bulking agents and freeze-drying parameters — not purity. Insist on a batch-specific certificate of analysis.

How peptides are made — the full pipeline

Research areas

  • Appetite regulation
  • Growth hormone regulation
  • Cachexia
  • Energy balance
  • Peptide hormones

Research-area guides

Latest research

Recent clinical trials and publications mentioning Ghrelin, pulled automatically from ClinicalTrials.gov and PubMed and refreshed daily. Listings are unfiltered search results, not curated endorsements.

Frequently asked questions

What is ghrelin?+

A stomach-derived hormone that is the body’s main hunger signal — it rises before meals to stimulate appetite and falls after eating. It also triggers growth-hormone release.

Why is ghrelin chemically unusual?+

It is the only known human hormone that needs a fatty-acid (octanoyl) group attached to one of its residues to work. The enzyme that adds it, GOAT, is a distinctive potential drug target.

How is ghrelin related to growth-hormone peptides?+

Ghrelin is the natural ligand of the growth-hormone secretagogue receptor — the same receptor that synthetic GHRPs like ipamorelin and hexarelin activate. Those drugs essentially mimic ghrelin’s growth-hormone action.

Is this medical advice?+

No — this is a research and educational reference, not dosing guidance.

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